Ionic Compound

Ionic compounds are basically defined as being compounds where two or more ions are held next to each other by electrical attraction

Ionic Compounds

This is a summary of the past and present nomenclature or naming conventions for ionic compounds

Naming Compounds

An ionic compound is one in which at least two of the elements or compounds in the group are oppositely-charged ions held together

Ionic Compounds

Ionic compounds generally are very hard and have very high melting points. They are solids at room temperature

Face Centered Cubic

When metals react with non-metals they form an ionic compound. Ions have a charge because electrons are lost or gained in forming an ionic bond.

Showing posts with label ionic compounds. Show all posts
Showing posts with label ionic compounds. Show all posts

Tuesday, December 27, 2011

basically defined ionic compounds



Ionic compounds are basically defined in such a way that compounds containing two or more ions are considered alongside electrical attraction. One of the positively charged ions (called "cations") and the second is a negative charge ("anion"). Cations are usually the metal atoms and anions are polyatomic ions or metals (ions with more than one atom). Thinking about school: the same thing that makes the positive and negative ends of the magnet attached to one another, which makes the cations and anions cling to each other.

Usually, when we are ionic compounds, forming large crystals, you can see with the naked eye. Table salt is an example of this - if you look at a salt crystal, it is likely that you will be able to see which looks a bit 'like a cube. This is because the salt as a stack of small cube-shaped.

Sometimes, when you see the salt, dust appears in place of the cube. This does not mean that salt is not a crystal - it means that the crystals are so small that you can not see with the naked eye. If you were to put the dust under a microscope, chances are you've seen a bit 'of geometric blocks.

So what are the important properties of salts? Well, I'm sure glad you asked ...

All ionic compounds form crystals. As far as I know, there are exceptions. Once again, the desire to form salt crystals, because when there is a whole series of small positive and negative electrical charges, all stuck together, seem to be happy bunch of small groups of stacking. The arrangement of these ions as part of a stack is different, and is called "unit cell". There are a dozen different types of cells generic units. When you graduate, you ask them. High school classes, it really is not so important.

Ionic compounds tend to have high melting and boiling points. When I say "high", which I think is "very, very high." Most of the time when working with ionic compounds in a chemistry class, the melting temperature is warm enough that you can not melt them with a Bunsen burner. So why such high temperatures? Well, it has to do with how the ionic materials are held together. Remember how we said earlier that crystals form ionic compounds? These crystals are really just great big blocks of positive and negative charges while being held. To break the positive and negative charges apart, it takes a tremendous amount of energy. This means that if we heat the fabric to add energy, it requires an enormous amount of energy to break.

Ionic compounds are very hard and very fragile. Again, it is because of how they stick together. Above we said that it takes a lot of energy to break the positive and negative charges apart. This is why ionic compounds are so difficult - it simply does not move much, so it does not bend at all. This also explains the fragility of the ionic compounds. It takes lots of energy for ionic charges of others. However, if we give a large crystal hit hard enough with a hammer, usually end up with more energy to break the glass the glass is not broken in one place, but a lot of places. Instead of cutting to the chase, is shattered.

Of electricity when ionic compounds dissolve in water. If we take salt and dissolved in water, the water molecules pull the positive and negative ions from each other. (This is due to the unusual properties of water, but it's a different story a different time). In contrast, the ions adjacent to each other, walking around in water. Now, think about what that power is - I hope you remember that electricity is only the movement of electrons through the metal (or elsewhere). Now, the electrons are the only negatively charged particles, and metals are the property of their own good, allowing them to go around. The salts are dissolved in the same way. When the salt dissolves in water, positive and negative ions in the water with the electrons to flow much better than if just had the water itself. Voila! The salt water does! The question is, maybe it is, "'the flow of electricity through crystals of salt?" Nope. It does not.

Because the ions are trapped in a place due to the crystal structure is electrically not move very well. Another good question: "Is the water without salt in the conduct electricity?" The answer: Not very well. The water itself is a lousy leader. The reason that sets hair in Boneheads the bath with them again in the donut man is that when they wash all the dirt on them will be dissolved in water. Some of ionic impurities, so when the dryer hit the water, they get zapped . A "thought experiment" It would be interesting to wash all the salt for yourself and then drop a hairdryer in the bath with you. In theory, you would be fine. In real life, would you still become a creature crunch because the tap water itself, there are ionic compounds dissolved in anyway.

ionic bonding puzzle



Ionic Bonding Puzzle Lab

Introduction

When metals and non-metals chemically react, the atoms will tend to form ions or charged atoms. Ions form because electrons are either gained or lost. Metals will generally form cations or positive ions, since they tend to donate electrons Non-metals will form anions or negative ions, since they tend to accept electrons.

Activity

In this activity you will create models of ionic compounds and observe the chemical formula of the binary molecules you have created. Your data will be recorded in a data table or chart, similar to the one below.

Cation name
Anion name
Chemical Formula
Name





Discussion/Conclusion (talk with your classmates and address in your write-up)

·         Notice the shape and charge of each cation model. Why do you think there are slots in the metal atoms? (TIP: How do the atoms become ions?)

·         Notice the shape and charge of the anion models. Why do you think there are tabs in the non-metal atoms?

·         If you were to make a neutral atom following the model, what would the shape be?

·         Group the ion models by family. What do you notice about the number of tabs or slots? What do you notice about the tabs or slots and charge of all ions? Is there a pattern? Why do you think the model is made that way?

·         In the compounds you formed, what do you notice about the ion charges, the net or final charge of the compound and how the charge relates to the chemical formula of the compound?

·         What do you notice about the names of the cations and anions on the cards. How do they compare with the name of the neutral atom or element. Do all metals have a number in parenthesis? Do the non-metals have anything in common about their name?

·         Is there a pattern between elements in a group or family and any numbers on the Periodic Table? (TIP: Think octet rule and how many electrons are involved to meet octet.)



Ionic Bonding Model Lab Scoring Rubric

4
Lab format follows the expected guidelines in the handout. Blank page on left for scores, Title, Purpose, Materials, Procedure, Data table, Discussion/Conclusion.

Data is organized into a table with the names of cation, anion, chemical formula and compound name.

Discussion and Conclusion addresses:
  • Explain how the model relates to the ion; number and shape of slot, (ie. charge, cation, anion), what a neutral atom would look like in the model.
  • Explain how elements are organized on the Periodic Table of Elements (i.e the category; metal or non-metal; and charge of the ion; amount of charge and position on the Periodic Table of Elements related to the valence electrons.
  • Explain the connection between the ion charge and the ratio of atoms in the chemical formula for the ionic compound (the pieces fit together to balance charge)
  • Identify the similarity in the name for all non-metal anions, similarity in the name for Alkai Metal and Alkaline Earth Metal cations; similarity in the name for all other metal cations.

3
Lab format follows the guidelines in the handout. Blank page on left for scores

Data does not have 40 combinations, cation name, anion name, charge chemical symbol, and chemical name

Missing some topics in the discussion or there is some incorrect information in parts of Discussion/Conclusion or data table.

2
Formatting problem

Conceptual errors when writing chemical formula or name of compounds

Missing or incorrect information in many parts of the Discussion/Conclusion

1
Major problems or conceptual errors.











Ionic Bonding Puzzle Lab Notes

The Model

Metals ___________ electrons and become positive ions or ______________.
Non-metals __________ electrons and become negative ions or _____________.
lose, cations, gain, anions


                     neutral atom                                                                    ions





                          metal                                    à




                       non-metal                               à





Using the same analogy for the atom, what would a +2 cation and a -2 anion look like?







Bonding and Predicting Chemical Formulas

Al2O3



The ______________ show the ___________ of each atom in the ________________.
subscripts, ratio, compound

For an ionic bond, the ________ need to balance _____________. The _____________ of each ion changes to make the compound _____________. The chemical ___________ shows how many of each ion are needed to _____________ the ____________ and make the compound neutral.
Ions, charge, number, neutral, formula, balance

What ratio will the +1 and -1 ions combine to balance the charge?



                                  +                                                        à




What ratio will the +2 and -1 ions combine to balance the charge?




                                  +                                                         à
 




Naming or Nomenclature

Use the name on the puzzle pieces to determine the name of each compound you created. TIP: In this lab if you create binary compounds you will save yourself time.

What do all of the Type II ions have in common?




What does the Roman Numeral show for a Type II ion?




Notice the Type ____ ions do not have a Roman Numeral. What are the charges of an ion formed from a Type I metal?





What do all ________ atomic non-metals or _______________ have in common?
mono-, anions





TIP: To make a subscript for a chemical formula, highlight the number and from the menu bar, select Format > Font > Subscript or A2 on the Font Formatting Pallette

 











compounds can be molecular or ionic

The compounds can be molecular or ionic


Substances can be classified as molecular compounds or ionic compounds.

(. Pronounce "eye'-ons") are ionic compounds composed of ions Ions are atoms or molecules that have a global charge: positively charged ions are called cations (pronounced "Eye-cat'-ons") and negatively charged ions are called anions (pronounced "an eyes-ons"). A molecule that carries a positive or negative overall charge is called a polyatomic ion. Ionic compounds can be recognized as compounds formed by a metal attached to a nonmetal or polyatomic ion containing compounds.

Molecular compounds are those that contain only non-metals are glued together, and where there are polyatomic ions are present.

CaCl2 is an ionic compound containing a metal and attached to a metal does not.

NH4NO3 is an ionic compound because it contains at least one polyatomic ion. (More information about polyatomic ions later ...)

NH3 and H2O would be molecular compounds that contain only nonmetals bonded together and there are polyatomic ions.

The smallest unit of a molecular compound is a molecule. In an ionic compound, there is no molecule units, but there is a matrix or network of repeating units of cations and anions, which we call a "unit of the formula."

Writing formulas for binary ionic compounds

Binary ionic compounds, as its name suggests, consists of two elements. How to write the correct formula for ionic compounds formed between a metal and non metal? There are three steps, you will remember them by practicing how to write formulas.

1. Insert a symbol of the cation, then the symbol of an anion. And 'ionic compound formed between magnesium and chlorine, writes Mg 2 Cl-1.

2. Cruz taxes and the load on the cation becomes the index for the anion and the charge for the anion becomes the subscript for the cation. Thus in the example of magnesium chloride, can be written MgCl 2 -1. Place the positive and negative signs. For magnesium chloride, the formula would MgCl2. (If the index is 1, not written.)

3. Reduce and simplify so that the rates are the lowest of integers. For example, the ionic compound formed between calcium and sulfur, Ca +2 and S-2   Ca2S2 CaS.

4. Even if an ionic compound is composed of charged particles, should be combined so that the compound has a net charge of zero, so that the compound is neutral.

Monday, August 15, 2011

How ionic compounds Workstation


How ionic compounds Workstation


All ionic compounds are made up of tiny crystalline structures, which consist of positively charged particles called cations and negatively charged particles known as anions. In an ionic substance. Cations and anions to form a grid band that is very hard and brittle when you are in a solid state, ionic compounds are good electrical conductors because their ions can not move much. In an ionic liquid or substance which was dissolved in a polar solvent, however, is an ionic compound the ions are separated and allow electrons to move freely between them.

Applications

Ionic compounds have many uses. Table salt is an ionic compound. In fact, all forms of ionic salts. As a result, ionic compounds are mixed with other substances to produce different properties or divided in a solvent and used for their electrical conductivity or other purposes. Ionic compounds are also widely used in textile processing industry to remove stains from fabrics.

Benefits

Ionic compounds have several important advantages. They have very high melting and boiling points because their ions are linked together so well. Ionic compounds are very strong and are hard to break. Ionic compounds such as water, alcohol, acetone or other polar solvent dissolved provide high electrical conductivity. They are usually nontoxic, nonflammable, and can be produced from a number of different elements. Moreover, the ratio of cations and anions in an ionic compound can vary, causing different properties to be produced.

Disadvantages

Although ionic compounds are beneficial, but also have several disadvantages. For example, ionic solid compounds are very fragile and tend to break when broken. Ionic compounds have low thermal conductivity are usually solid at room temperature.

Saturday, July 30, 2011

Ionic Compounds Study Guide


Ionic Compounds


Binary Compounds I & II

            1. Binary Compounds I
A. Identification
1. Metal – Nonmetal (no O present)
                                    2. Metal salts
                                    3. non-metal suffix – “ide”
                        B. General Hazards
                                    1. Water reactive
                                    2. Alkali solutions
                                    3. Flammable Toxic Gas
                        C. Examples
                                    1. Potassium Sulfide
                                    2. Aluminum Cloride
                                    3. Calcium Nitride

            2. Binary Compounds II
                        A. Identification – same as Binary I
                                    1. Metals have the potential to have multiple charges
                                    2. non-metal suffix – “ide”
                                    3.Metal suffix – “ous” for lower valence; “ic” for higher valence
                                                1. Systematic naming – Roman Numeral I & II
                        B. General Hazards
                                    1. Water reactive
                                    2. Alkali solutions
                                    3. Flammable Toxic Gas
                        C. Examples
                                    1. Cuprous Cloride or Copper II Cloride
                                    2. Cobaltous Cloride or Cobalt II Cloride
                                    3, Ferrous Cloride or Iron Cloride

Metal Oxides – Metal Oxide Salt
A. Identification
                        1. Metal with one oxygen
                        2. Metal named first w/ non-metal oxygen identified as “oxide”
            B. General Hazards
                        1. water reactive w/ heat generated with reaction
                        2. corrosive solution – depending on base metal
                                    a. if O attached to alkali metal, corrosivity increases
                                    b. may act as an oxidizer
            C. Examples
                        1. Aluminum Oxide
                        2. Arsenic Oxide
                        3. Beryllium Oxide

Inorganic Peroxides

          A. Identification
1.Similar to metal oxides; instead of 1 O attached, 2 O attached
                        2. Peroxide complex – an anion
                        3. A metal + peroxide ion
                        4. dioxide sometimes used in the name
            B. General Hazards
                        1. Heat generated w/reaction
                        2. Strong oxidizers
                        3. Water reactive
                        4. Corrosivity depends upon base metal
            C. Examples
                        1. Barium Peroxide
                        2. Calcium Peroxide
                        3. Cesium Peroxide

Oxygenated Inorganic Compounds ( Oxy Salts )

          A. Identification
                        1. Metal + Non-metal oxygenated ion
                                    a. Oxy ions are covalently bonded
                        2. The state of the compound identifies the prefix and suffix used
3. Naming configuration starts with the normal oxygenated state of  the oxy ion
            a. More than one O – Prefix “Per” Suffix “ate”
            b. Normal state of O -                     Suffix “ate”
            c. Less than one O -                         Suffix “ite”
            d. Less than two O – Prefix “Hypo” Suffix “ite”

                                    a. Base naming for oxy ions – Normal State – suffix “ate” (-1 ions)
                                                1. Chlorate ClO3
                                                2. Bromate BrO3
                                                3. Iodate IO3
                                                4. Nitrate NO3
                                                5. Manganate MnO3
                                    b. Base naming for (-2 ions)
                                                1. Carbonate CO3
                                                2. Sulfate SO4
                                    c. Base naming for (-3 ions)
                                                1. Phosphate PO4
                                                2. Borate BO3
                                                3. Arsenate AsO4


                        4. Example
                                    NaClO4 Sodium Perchlorate
                                    NaClO3 Sodium Chlorate
                                    NaClO2 Sodium Chlorite
                                    NaClO   Sodium Hypochlorite

Metal Hydroxides

          A. Identification
                        1. Compounds that combine a metal and the hydroxide radical OH
                        2. The name of the metal + “hydroxide”
                        3. OH has a valence of -1
            B. General Hazards
                        1. Produce heat during reaction
                        2. If mixed with water, produces a caustic solution
                        3. Corrosive qualities dependent on the base metal
            C. Examples
                        1. Aluminum Hydroxide
                        2. Beryllium Hydroxide
                        3. Cesium Hydroxide
                        4. Potassium Hydroxide

Inorganic Acids (Do not confuse with Binary Acids)

          A. Identification
                        1. Hydrogen + Polyatomic Non –metal
                        2. Naming configuration
                                    a. Normal base state of the poly ion is identified
                                    b. Name ends w/acid
                                    c. Look at the number of oxygens in the poly/NM
                                                1. More than 1  – Prefix “Per”    Suffix “ic”
                                                2. Normal state   -                          Suffix “ic”
                                                3. Less than 1  -                              Suffix “ous”
                                                4. Less than 2  – Prefix “Hypo”  Suffix “ous”
            B. General Hazards
                        1. Toxic Corrosive
                        2. Corrosive poison
                        3. Oxidizer
            C. Examples
                        1. Hypochlorous Acid
                        2. Boric Acid
                        3. Sulfuric Acid
                        4. Nitrous Acid



Binary Acids (Do not confuse with Inorganic Acids)

          A. Identification
                        1. H + NM from VIB or VIIB – Hydrogen Halides
                        2. Gaseous in pure form
                        3. Aqueous when placed in water
4. H is changed to hydro; NM ending becomes “ic”; the word acid is added to the end
            B. General Hazards
                        1. Toxic corrosive
                        2. Corrosive poison
                        3. Poison
            C. Examples
                        1. Hydrobromic acid
                        2. Hydrofluoric acid
                        3. Hydrochloric acid

Hydrates

          A. Identification
                        1. Have water included in the molecule
                        2. Appear wet; however are extremely dry substances
                        3. Can be identified by the “ ·  ” in the formula
                        4. Salt · H20
                                    a. Name the salt
b. Identify the number of water molecules ( utilize greek numbering system – (1)mono, (2)di, (3)tri, (4)tetra, (5) penta, (6)hexa, (7)hepta, (8)octa
                                    c. End with “hydrate”
            B. General Hazards
                        1. Strong affinity for water
            C. Examples
                        1. Barium Hydroxide Octahydrate
                        2. Aluminum Oxide Trihydrate












Binary Non-salts

A. Identification
            1. NM + NM
            2. No Carbon within the compound
            3. No polyatomic ion present
            4. Greek numbering system used
            5. Name of NM, then Greek number of the second NM and end in “ide”
B. General Hazards
            1. Flammable
            2. water reactive
            3. Toxic
            4. Oxidizer
            5. Release of flammable and toxic gases
C. Examples
            1. Iodine Pentafluoride
            2. Bromine Pentafluoride
            3. Phosphorous Heptasulfide

Non-Metal Oxides

A. Identification
            1. Name the principle atom that is not oxygen
            2. Count the number of oxygen atoms, and apply the Greek number
            3. End with “oxide”
B. General Hazards
            1. Commonly found in products of combustion
                        a. Asphyxiants
                        b .Irritants
                        c. Carcinogens
C. Examples
            1. Sulfur Dioxide
            2. Sulfur Trioxide
            3. Carbon Monoxide

Ammonia, Cyanide, and Azide Compounds

            

Thursday, July 28, 2011

Rules for Writing Formulas for Ionic Compounds



Rules for Writing Formulas for Ionic Compounds

1.     Write the metal symbol first and then the non metal symbol second.
Ca                           I
2.     Write the cation charge above the metal and the anion charge above the non metal
2+                         1-
       Ca                     I
3.     Do the crossover rule and write the charge for the cation as a subscript for the non metal symbol and the charge for the anion as a subscript for the metal.
2+                         1-
                       Ca                    I     à CaI2     ß subscript goes at the                                                                                                                         bottom of the symbol
                                                                        and is smaller.

Rules for Naming Ionic Compounds

First Word – Name of the metal
Second Word – Name of the non-metal end in “ide”
Ex: Calcium Iodide

Rules for Naming Ionic Compounds with Transition Metals
The stock naming system uses roman numerals to indicate the charge of the cation because they can have more than one charge.

First Word – Name of the metal
Roman numeral in brackets to indicate the charge
Second Word – Name of the non-metal end in “ide”

Ex:              FeCl3 is Iron (III) chloride
                   FeO is Iron (II) oxide
                   Cu2S is coper (I) Sulfide
                   PbO2 is lead (IV) oxide
How do I know the charge for iron is 3? I use the reverse crossover rule
                                                3+               1-
Ex:              FeCl3 à                   Fe               Cl à   Iron (III)Cloride

Rules for Naming Ionic Compounds with Transition Metals
The stock naming system uses roman numerals to indicate the charge of the cation because they can have more than one charge.

First Word – Name of the metal
Roman numeral in brackets to indicate the charge
Second Word – Name of the non-metal end in “ide”

Ex:              FeCl3 is Iron (III) chloride

Rules for Naming Ionic Compounds with Transition Metals

The classic naming system uses the latin word with the ending “ous” to indicate the transition metal’s with the lower ion charge and the ending “ic” to indicate the greater ion charge of the transition metal.

For example: Fe is Ferrum and can have a charge of +2 ferrous or +3 ferric.

Element
Latin Name
Ion with lower charge
Ion with Higher Charge
Iron

                                    
Fe2+

Fe3+
Copper
Cuprum 

Cu+

Cu2+
Lead
Plumbum

Pb2+

Pb4+

Formula
Classical System
Stock System
FeCl3
Ferric Chloride

FeO
Ferrous Oxide

Cu2S
Coprous Sulfide

PbO2
Plumbic Oxide


Write the chemical formula for each
a) Copper (I) Oxide
b) Lead (IV) Bromide
c) Iron (III) Sulfide
d) Nickel (III) Flouride
e) Manganese IV) Fluoride

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